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It depends what part of the world you're in. (see "DVD region code" on wikipedia for further details):

Region 1: Seasons 1-12 and 20 have been released as DVD boxsets, with Season 13 coming on August 24, 2010.

Region 2: Seasons 1-12, with Season 13 coming on September 13, 2010.

Region 4: Seasons 1-12 and 20, with Season 13 coming on Spetmeber 29, 2010.

Region 5: Seasons 1-5, with Season 6 coming on September 9, 2010.

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